{"id":139,"date":"2025-04-25T15:55:38","date_gmt":"2025-04-25T06:55:38","guid":{"rendered":"https:\/\/www.pla-mirai.net\/twinscrew-extruder\/?p=139"},"modified":"2025-06-20T18:40:56","modified_gmt":"2025-06-20T09:40:56","slug":"resin-degradation","status":"publish","type":"post","link":"https:\/\/www.pla-mirai.net\/twinscrew-extruder\/en\/improvement\/resin-degradation.html","title":{"rendered":"Reduce Quality Complaints and Waste Costs with Resin Degradation Prevention"},"content":{"rendered":"<p>Resin degradation is the root cause of quality complaints. Since it is directly related to trust in the material and the company, a single claim can result in the loss of profits and customers.<\/p>\n<p>From the perspective of generating trust and profit by protecting materials, this article will summarize the causes of deterioration and management risks, and provide details on effective process management and the use of twin-screw extruders as improvement measures.<\/p>\n<h2>Resin degradation is a hotbed of quality complaints<\/h2>\n<p>Even a single quality complaint for plastic products can cause tremendous losses to a company. The loss of customer trust and profits is immeasurable, and sometimes even market share can be affected.<\/p>\n<p>Especially defects that appear on the surface of plastic products,<span class=\"marker\">Invisible deterioration of the material itself<\/span>Therefore, it is necessary to take preventive measures to prevent deterioration from the raw material stage. This will greatly reduce product defect rates and improve yields.<\/p>\n<h2>Factors and effects of resin degradation<\/h2>\n<h3>Common Deterioration Mechanisms<\/h3>\n<p>One of the main mechanisms of resin degradation is the reheating of<span class=\"marker\">Molecular Chain Rupture<\/span>It is. Heating, especially at high temperatures for long periods of time, causes the molecular chains to break up, resulting in a resin that is less strong and more brittle.<\/p>\n<p>Anothe<span class=\"marker\">Water content and oxidation of raw materials<\/span>The appearance and hygiene of the product can also be compromised by problems such as discoloration of the resin, odor, and bubbles, depending on the Other,<span class=\"marker\">Excessive heat shear<\/span>is another factor in resin degradation. Thermal degradation can cause problems such as gas generation and carbon deposits.<\/p>\n<h3>Impact on Management Risk<\/h3>\n<p>What are the risks to business operations that can result from neglecting resin deterioration? The first risk is the cost of dealing with complaints, delays in delivery, and an increase in lost products. These negative effects on management are inevitable.<\/p>\n<p>Further,<span class=\"marker\">Risk of litigation or recall if serious<\/span>Once a customer trust relationship is lost, it is not easy to recover it, and the result can be a long-term loss of revenue. Once trust with customers is lost, it is not easy to regain it, and as a result, it may cause a long-term decline in profits, so early action is required.<\/p>\n<h2>How to Prevent Resin Deterioration? Introducing a basic approach<\/h2>\n<h3>Heating Management<\/h3>\n<p>To avoid unnecessary heat history,<span class=\"marker\">Optimization of temperature profiles and control of reheating<\/span>is essential. By optimizing the heating conditions, the destruction of the molecular structure can be prevented and the original performance of the resin can be maintained.<\/p>\n<h3>Moisture and oxygen management<\/h3>\n<p>To prevent resin degradation, it is also important to control moisture and oxygen in raw materials.<span class=\"marker\">Pre-drying and nitrogen purging<\/span>Thoroughly enforcing the following measures prevents deterioration due to oxidation and hydrolysis, and prevents deterioration in the appearance and physical properties of the product.<\/p>\n<h3>Utilization of stabilizers<\/h3>\n<p>Proper use of additives such as antioxidants, heat stabilizers, and UV absorbers protects the molecular structure of the resin and minimizes degradation.<span class=\"marker\">Selection of stabilizers according to application<\/span>is the point.<\/p>\n<h3>process optimization<\/h3>\n<p>Prevents excessive shearing and retention and suppresses bubble generation<span class=\"marker\">Kneading and devolatilization design<\/span>is required. Optimizing the entire process will enable consistent product quality and increased productivity.<\/p>\n<h2>Deterioration control realized by twin-screw extruder<\/h2>\n<p>The twin-screw extruder has been attracting attention as a device that can optimize the process for resin degradation countermeasures. The devolatilization mechanism eliminates the<span class=\"marker\">Effective removal of volatile components<\/span>will be.<\/p>\n<p>Anothe<span class=\"marker\">Designed to avoid overheating and overshearing<\/span>Another major advantage is that the molecular structure can be protected with<\/p>\n<p>In addition, anti-degradation agents and various stabilizers are<span class=\"marker\">Uniform kneading<\/span>This directly leads to longer product life. Twin-screw extruders are indispensable in preventing product problems and ensuring stable quality.<\/p>\n<div class=\"icon-head01\">Introducing CTE's twin-screw extruder, which is highly effective in resin degradation<\/div>\n<div class=\"low-left-img-box\">\n<div class=\"low-left-img\">\n    <img decoding=\"async\" src=\"https:\/\/www.pla-mirai.net\/twinscrew-extruder\/wp\/wp-content\/uploads\/product_htm.png\" alt=\"CTE twin-screw extruder_HTM type\"><\/p>\n<div class=\"caption\">Citation: CTE Official<br \/>\n      https:\/\/cte-japan.com\/en\/product\/htm-twin-screw-extruder\/<\/div>\n<\/p><\/div>\n<div class=\"low-left-img-catch\">HTM Twin-Screw Kneading Extruder<\/div>\n<p>The HTM twin-screw extruder has an intermeshing twin-screw structure with interdirectional rotation,<span class=\"marker\">High kneadability and excellent outgassing performance<\/span>The machine achieves the following. The high-speed rotor of the Banbury mixer type provides high shear to the resin, while repeated compression and release reduces heat generation, enabling low-temperature extrusion.<\/p>\n<p>It ensures uniform dispersion while preventing resin degradation and prevents the inclusion of air bubbles that can cause molding defects. This extruder is also suitable for processing high density filler and recycled materials, and has the ability to handle a wide range of materials.<\/p>\n<\/div>\n<div class=\"btn-web translation-block\"><a href=\"https:\/\/cte-japan.com\/en\/product\/htm-twin-screw-extruder\/\" target=\"_blank\" rel=\"nofollow\">See More at CTE.com<\/a><\/div>\n<div class=\"low-left-img-box\">\n<div class=\"low-left-img\">\n    <img decoding=\"async\" src=\"https:\/\/www.pla-mirai.net\/twinscrew-extruder\/wp\/wp-content\/uploads\/product_htm-tandem.jpg\" alt=\"CTE twin-screw extruder_HTM tandem type\"><\/p>\n<div class=\"caption\">Citation: CTE Official<br \/>\n      https:\/\/cte-japan.com\/en\/product\/htm-tandem-compounding-twin-screw-extruder\/<\/div>\n<\/p><\/div>\n<div class=\"low-left-img-catch\">HTM type tandem kneading extruder<\/div>\n<p>The HTM tandem extruder is based on the technology of the HTM twin-screw extruder and combines a twin-screw kneader and a large diameter single-screw extruder.<span class=\"marker\">High kneadability and outgassing performance<\/span>and in the single-axis extrusion section<span class=\"marker\">Low temperature, low speed<\/span>Extrusion is possible with<\/p>\n<p>It can process compounds with high filler concentration, recycled materials, and biodegradable resins in a stable manner while minimizing burnout and degradation. In addition, the segmentation of the screw allows for flexible handling of a wide variety of materials.<\/p>\n<\/div>\n<div class=\"btn-web translation-block\"><a href=\"https:\/\/cte-japan.com\/en\/product\/htm-twin-screw-extruder\/\" target=\"_blank\" rel=\"nofollow\">See More at CTE.com<\/a><\/div>\n<h2>What CTE twin-screw extruders can achieve<\/h2>\n<p>CTE's twin-screw extruders are capable of meeting material and molding challenges that were difficult to meet with conventional equipment, thanks to our reliable technology.<span class=\"marker\">Sensitive materials such as recycled materials with thermal history and biodegradable resins<\/span>But it can be extruded without loss of physical properties.<\/p>\n<p>Further,<span class=\"marker\">Drying process can be omitted or shortened.<\/span>This will also contribute to increased productivity.<\/p>\n<ul>\n<li><b>Degradation of physical properties is noticeable in materials with thermal history, such as recycled materials.<\/b><br \/>\u2192Repellet of recycled material, compared to engaged co-directional biaxial<span class=\"marker\">Deterioration was minimized and controlled.<\/span><\/li>\n<li><b>Insufficient pre-drying causes quality deterioration.<\/b><br \/>\u2192 PC (polycarbonate)<span class=\"marker\">Pre-drying time can be reduced to 1\/3 with no problem.<\/span>Extrusion could be done.<br \/>\u2192 With the installation of vacuum vents.<span class=\"marker\">No pre-drying<\/span>Extrusion molding is now possible with<\/li>\n<li><b>Trying to use biomass materials, but the quality deteriorates when blended.<\/b><br \/>\u2192Biodegradable resins such as PLA and PBAT mixed with filler<span class=\"marker\">Extrusion without quality deterioration<\/span><br \/>\u2192directional marker or indicator<span class=\"marker\">Biomass materials such as wood flour and starch<\/span>and resin can be extruded without burning the material.<\/li>\n<\/ul>\n<h3>Data showing performance of CTE products<\/h3>\n<h4>MFR comparison of biodegradable resin compounds<\/h4>\n<h5>Prevents degradation by suppressing MFR increase even with high throughput<\/h5>\n<table>\n<tbody>\n<tr>\n<th>(data) item<\/th>\n<th>unit<\/th>\n<th>CTE HTM Tandem Extruder<br \/>(Non-intermeshing, interdirectional rotation)<\/th>\n<th>Tandem extruders from other manufacturers<br \/>(Engagement and co-directional rotation)<\/th>\n<\/tr>\n<tr>\n<th>Screw diameter<\/th>\n<th>mm<\/th>\n<td>50<\/td>\n<td>46<\/td>\n<\/tr>\n<tr>\n<th>throughput<\/th>\n<th>kg\/h<\/th>\n<td>200<\/td>\n<td>50-130<\/td>\n<\/tr>\n<tr>\n<th>Screw rotation speed<\/th>\n<th>rpm<\/th>\n<td>280<\/td>\n<td>120-180<\/td>\n<\/tr>\n<tr>\n<th>Extrusion grade<\/th>\n<th>g\/10min<\/th>\n<td>0.6<\/td>\n<td>3.3<\/td>\n<\/tr>\n<tr>\n<th>Injection grade<\/th>\n<th>g\/10min<\/th>\n<td>25<\/td>\n<td>39<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<div class=\"caption\">*Data provided by CTE<br \/>PBAT:CaCO3=53:47 (extrusion grade). PBAT:CaCO3=75:25 (injection grade)<\/div>\n<p>In the blending of biodegradable resin (PBAT) with CaCO\u2083, CTE's twin-screw extruder showed an MFR of only 0.6 g\/10 min after extrusion, even when operated at high throughput (200 kg\/h) and high speed (280 rpm).<\/p>\n<p>The CTE machine shows a small decrease in molecular weight, confirming that degradation is suppressed.<span class=\"marker\">Does not compromise the physical properties of biodegradable resins and does not reduce productivity<\/span>The performance is suitable for processing sites.<\/p>\n<h4>Comparison of die tip resin temperature<\/h4>\n<h5>Small deviation between set temperature and actual temperature, suppressing thermal degradation<\/h5>\n<table>\n<tbody>\n<tr>\n<th>(data) item<\/th>\n<th>unit<\/th>\n<th>CTE HTM Tandem Extruder<\/th>\n<th>Conventional twin-screw extruder<\/th>\n<\/tr>\n<tr>\n<th>throughput<\/th>\n<th>kg\/h<\/th>\n<td>100<\/td>\n<td>50<\/td>\n<\/tr>\n<tr>\n<th>Screw rotation speed<\/th>\n<th>rpm<\/th>\n<td>140<\/td>\n<td>500<\/td>\n<\/tr>\n<tr>\n<th>Die tip resin temperature ratio<\/th>\n<th>SV<\/th>\n<td>180<\/td>\n<td>180<\/td>\n<\/tr>\n<tr>\n<th>Resin temperature<\/th>\n<th>&#8451;<\/th>\n<td>180<\/td>\n<td>204<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<div class=\"caption\">*Data provided by CTE<\/div>\n<p>In the HTM tandem extruder, when the die temperature is set at 180\u00b0C, the actual resin temperature is also stable in the 180\u00b0C range,<span class=\"marker\">Unnecessary temperature increase is not occurring<\/span>.<\/p>\n<p>In general, when resin is heated above the set temperature, thermal degradation such as molecular chain scission and yellowing is likely to occur. A small discrepancy between the set temperature and actual temperature indicates an extrusion environment that can maintain stable quality.<\/p>\n<div class=\"conclusion-box-frame\">\n<div class=\"l-stack-small\">\n<div class=\"conclusion-box-ttl\">\n<div class=\"conclusion-box-ttl__icon-frame\">\n<div class=\"conclusion-box-ttl__icon\"><span>summary<\/span><\/div>\n<\/p><\/div>\n<div class=\"conclusion-box-ttl__text\">Preventing deterioration is the first step in protecting quality and reliability.<\/div>\n<\/p><\/div>\n<div class=\"conclusion-box-content\">\n<p>How to control resin degradation and maintain stable quality is an important theme that relates not only to product reliability but also to the company's continued growth. In recent years, in particular, there has been an increase in difficult-to-handle materials such as recycled materials and biodegradable resins, and the selection of equipment that can accurately process these materials is required.<\/p>\n<p>CTE twin-screw extruders are,<span class=\"marker\">Designed for stable extrusion without compromising material characteristics<\/span>is applied. If you are interested in preventing quality problems or improving productivity, please contact us through the official CTE website.<\/p>\n<div class=\"btn-web translation-block\"><a href=\"https:\/\/cte-japan.com\/en\/contact\/\" target=\"_blank\" rel=\"nofollow\">Contact CTE <br \/>for a Consultation<\/a><\/div>\n<\/p><\/div>\n<\/p><\/div>\n<\/div>","protected":false},"excerpt":{"rendered":"<p>Resin degradation is the root cause of quality complaints. Since it is directly related to trust in the material and the company, a single claim can result in the loss of profits and customers. This article summarizes the factors of degradation and management risks from the perspective of generating trust and profit by protecting materials, and discusses how to improve [...].<\/p>","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[8],"tags":[],"class_list":["post-139","post","type-post","status-publish","format-standard","hentry","category-improvement"],"acf":[],"_links":{"self":[{"href":"https:\/\/www.pla-mirai.net\/twinscrew-extruder\/en\/wp-json\/wp\/v2\/posts\/139","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.pla-mirai.net\/twinscrew-extruder\/en\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.pla-mirai.net\/twinscrew-extruder\/en\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.pla-mirai.net\/twinscrew-extruder\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.pla-mirai.net\/twinscrew-extruder\/en\/wp-json\/wp\/v2\/comments?post=139"}],"version-history":[{"count":5,"href":"https:\/\/www.pla-mirai.net\/twinscrew-extruder\/en\/wp-json\/wp\/v2\/posts\/139\/revisions"}],"predecessor-version":[{"id":427,"href":"https:\/\/www.pla-mirai.net\/twinscrew-extruder\/en\/wp-json\/wp\/v2\/posts\/139\/revisions\/427"}],"wp:attachment":[{"href":"https:\/\/www.pla-mirai.net\/twinscrew-extruder\/en\/wp-json\/wp\/v2\/media?parent=139"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.pla-mirai.net\/twinscrew-extruder\/en\/wp-json\/wp\/v2\/categories?post=139"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.pla-mirai.net\/twinscrew-extruder\/en\/wp-json\/wp\/v2\/tags?post=139"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}